Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K

Ultrasonic Velocity, Density and Viscosity of Binary Liquid Mixtures of Acetone with Toluene, Chlorobenzene and Nitrobenzene

We report the measurements of the speed of sound in the binary liquid mixtures of acetone with toluene, chlorobenzene and nitrobenzene measured at 303 K. The studies on ultrasonic velocity, density and viscosity in binary liquid mixtures have been used to evaluate the different thermo acoustical parameters along with the excess properties. It was found that in all the cases, the experimental da...

Measurement of Volumetric and Viscometric Properties of Binary Mixtures of Methyl Tert-butyl Ether (MTBE) + 1-Alcohol from 293.15 to 308.15 K and at Atmospheric Pressure

Densities and viscosities of binary mixtures of methyl tert-butyl ether (MTBE) with 1-alkanols include 1-butanol, or +1-pentanol, or +1-hexanol, or +1-heptanol were measured as a function of composition from 293.15 to 308.15 K at atmospheric pressure. The temperatures studied were 293.15, 298.15, 303.15 and 308.15 K. The experimental results have been used to calculate the viscosity de...

Compressed Liquid Densities for Binary Mixtures at Temperatures from 280- 440K at Pressures up to 200 MPa

A method for predicting liquid densities of binary mixtures from heat of vaporization and liquid densityat boiling point temperature (ΔHvap and n b ρ ) as scaling constants, is presented. B2(T) follows a promisingcorresponding-states principle. Calculation of α(T) and b(T), the two other temperature-dependentconstants of the equation of state, are made possible by scaling. As a result ΔHvap and...

Molecular Interaction Studies in Binary Liquid Mixtures Using Ultrasonic Techniques

Recently Khasare derived an equation of state for L-J fluid by modifying an expression for work done, obtained from partition function through perturbation approach .This is achieved by inserting at some fixed position in the m-component fluid, a single solute particle of radius ‘R’ in n-dimensions along with the necessary thermodynamic requirements. It was therefore thought worthwhile to under...

Dielectric Study on Polar Binary Mixtures of (Ester-Alcohol) at 298.2 K